Common surfaces · six structure families

Common surfaces and adsorption sites

Compare how FCC, BCC, HCP, SC, SH, and BCT crystals respond to common crystallographic cuts. Each guide connects the Miller plane, exposed atomic structure, subsurface registry, adsorption sites, and a rotatable slab.

Build any indexed surface

New to the notation? Begin with how Miller planes cut a bulk crystal.

The shade of the atoms indicates the depth of the layer, where paler atoms sit lower. Orange numbers mark constructed adsorption sites.

Face-centred cubic (FCC)

Close-packed faces, open rows, and regular steps
FCC(100) atomic surface net

FCC(100) →

A square surface net with a distinctive fourfold hollow.

ontopbridgehollow
FCC(110) atomic surface net

FCC(110) →

Dense atomic rows separated by open, directional troughs.

ontopshort bridgelong bridge+1 sites
FCC(111) atomic surface net

FCC(111) →

The close-packed triangular net with FCC and HCP hollows.

ontopbridgeFCC hollow+1 sites
FCC(210) atomic surface net

FCC(210) →

A strongly tilted (100)-like surface with closely spaced ledges.

ridge ontoplower-row ontopridge bridge+2 sites
FCC(211) atomic surface net

FCC(211) →

Narrow close-packed terraces separated by straight monatomic steps.

terrace ontopstep-edge ontoplower-step ontop+5 sites
FCC(221) atomic surface net

FCC(221) →

A compact stepped net close in orientation to the (111) face.

ledge ontoplower-row ontopledge bridge+4 sites
FCC(310) atomic surface net

FCC(310) →

Wider (100)-like terraces with long, directional channels.

terrace ontopraised-row ontoprow bridge+5 sites
FCC(311) atomic surface net

FCC(311) →

Short square terraces interrupted by close-packed step rows.

terrace ontopstep-edge ontoplower-row ontop+5 sites
FCC(331) atomic surface net

FCC(331) →

A vicinal (111) face with regular straight ledges.

terrace ontopledge ontoplower-step ontop+5 sites
FCC(511) atomic surface net

FCC(511) →

Broad square terraces separated by regularly spaced ledges.

terrace ontopstep-edge ontoplower-step ontop+5 sites

Body-centred cubic (BCC)

Dense (110), open low-index faces, and stepped rows
BCC(100) atomic surface net

BCC(100) →

A square net whose registry alternates through the body centre.

ontopbridgehollow
BCC(110) atomic surface net

BCC(110) →

The densest BCC face, with zig-zag rows and anisotropic bridges.

ontopshort bridgelong bridge+1 sites
BCC(111) atomic surface net

BCC(111) →

An open threefold surface built from several closely spaced levels.

outermost ontoplower-row ontoprow bridge+1 sites
BCC(210) atomic surface net

BCC(210) →

A highly open BCC face with sharp ridges and deep channels.

ridge ontoplower-row ontopridge bridge+2 sites
BCC(211) atomic surface net

BCC(211) →

Narrow BCC terraces with staggered, directional ledges.

terrace ontopstep ontoplower-row ontop+4 sites
BCC(310) atomic surface net

BCC(310) →

Broader BCC terraces separated by straight raised rows.

terrace ontopraised-row ontoplower-row ontop+4 sites

Hexagonal close packed (HCP)

Basal, prismatic, and pyramidal cuts
HCP(0001) atomic surface net

HCP(0001) →

The close-packed HCP basal plane with ABAB stacking.

ontopbridgeFCC hollow+1 sites
HCP(10-10) atomic surface net

HCP(10-10) →

A nonpolar prism face with distinct basal and c-axis rows.

raised-row ontoplower-row ontoprow bridge+2 sites
HCP(11-20) atomic surface net

HCP(11-20) →

A prism cut rotated 30° from HCP(10-10).

outer-row ontoplower-row ontopaxial bridge+3 sites
HCP(10-11) atomic surface net

HCP(10-11) →

An oblique HCP cut with mixed basal and axial character.

ridge ontoplower-row ontopridge bridge+2 sites
HCP(10-12) atomic surface net

HCP(10-12) →

A second pyramidal inclination with broader projected terraces.

terrace ontopridge ontoplower-row ontop+4 sites
HCP(11-21) atomic surface net

HCP(11-21) →

A rotated pyramidal cut with strongly staggered ledges.

ledge ontopterrace ontoplower-row ontop+4 sites

Simple cubic (SC)

Square and triangular nets with open stepped faces
SC(100) atomic surface net

SC(100) →

A primitive square net with ontop, bridge, and fourfold hollow sites.

ontopbridgefourfold hollow
SC(110) atomic surface net

SC(110) →

A rectangular simple-cubic face with two bridge directions.

ontopshort bridgelong bridge+1 sites
SC(111) atomic surface net

SC(111) →

A triangular net with two subsurface-distinct threefold hollows.

ontopbridgeL2-registry hollow+1 sites
SC(210) atomic surface net

SC(210) →

A short-period staircase of ridges and lower rows.

ridge ontoplower-row ontopridge bridge+2 sites
SC(211) atomic surface net

SC(211) →

Corrugated oblique ledges with mixed-height pockets.

ledge ontoplower-row ontopledge bridge+2 sites

Simple hexagonal (SH)

AA-stacked basal, prismatic, and pyramidal cuts
SH(0001) atomic surface net

SH(0001) →

A triangular basal net with direct AA layer registry.

ontopbridgethreefold hollow
SH(10-10) atomic surface net

SH(10-10) →

A rectangular prism net with basal and axial bridges.

ontopbasal bridgeaxial bridge+1 sites
SH(11-20) atomic surface net

SH(11-20) →

The second prism orientation, rotated 30° in the basal plane.

ontopaxial bridgecross-row bridge+1 sites
SH(10-11) atomic surface net

SH(10-11) →

An oblique pyramidal face with mixed basal and axial character.

ridge ontoplower-row ontopridge bridge+2 sites

Body-centred tetragonal (BCT)

Basal, prismatic, mixed-index, and stepped faces with independent a and c
BCT(001) atomic surface net

BCT(001) →

A square basal face with c-dependent alternating layers.

ontopbridgefourfold hollow
BCT(100) atomic surface net

BCT(100) →

A rectangular prism face that makes a and c visibly independent.

ontopbasal bridgeaxial bridge+1 sites
BCT(110) atomic surface net

BCT(110) →

A centred rectangular net with three distinct bridge geometries.

ontopdiagonal bridgebasal bridge / fourfold channel+1 sites
BCT(101) atomic surface net

BCT(101) →

A mixed basal–axial face whose inclination depends on c/a.

outermost ontoplower-row ontoprow bridge+2 sites
BCT(111) atomic surface net

BCT(111) →

An open distorted-triangular face with closely spaced sublayers.

outermost ontoplower-row ontoprow bridge+2 sites
BCT(211) atomic surface net

BCT(211) →

A c/a-dependent stepped face with oblique ledges.

ledge ontoplower-row ontopledge bridge+2 sites

What are surface adsorption sites?

Surface adsorption sites are characteristic positions where an atom or molecule can begin interacting with a crystal surface. An ontop site lies above one surface atom, a bridge site spans two neighbouring atoms, and a hollow site sits among three or more atoms. The available sites change with the crystal lattice and Miller indices because every cut exposes a different atomic pattern.

The guides above document familiar low- and high-index facets. For a plane not listed here, use the interactive surface builder to generate its bulk cut, surface cell, atomic layers, and geometric adsorption-site candidates.